3820 SDS
===================================================================================================================
Section 1 -- PRODUCT AND COMPANY IDENTIFICATION
===================================================================================================================
HMIS CODESHealth 3
3820 Flammability 3
Reactivity 0
MANUFACTURER'S NAME: ADDRESS:
Cumberland Products Incorporated 50 Commerce Parkway
Hodgenville, KY 42748
EMERGENCY PHONE : (800) 424 - 9300 DATE PRINTED : 11/27/2013
INFORMATION PHONE : (800) 223 - 1918
FAX NUMBER : (800) 500 – 9812
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Section 2 -- COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
===================================================================================================================
% by WT CAS No. INGREDIENT UNITS VP
0.1 - 1% 1330-20-7 Xylene 8
ACGIH TLV 100
ACGIH STEL 150
OSHA PEL 100
OSHA STEL
NIOSH STEL: 150
NIOSH REL: 100
0.1 - 1% 100-41-4 ethylbenzene 7
ACGIH TLV 100
ACGIH STEL 125
OSHA PEL 100
OSHA STEL N/E
NIOSH 100 (TWA)
NIOSH 125 (STEL)
NIOSH 800 (IIDLH)
5 - 20% 110-43-0 Methyl n-Amyl Ketone 3
ACGIH TLV 50
ACGIH STEL N/E
OSHA PEL 100
OSHA STEL N/E
NIOSH REL-100
NIOSH REL-C: 800
1 - 5% 95-63-6 1,2,4-Trimethylbenzene N/A
ACGIH TLV 25
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
NIOSH 25
5 - 20% 67-64-1 Acetone 180
ACGIH TLV 500
ACGIH STEL 750
OSHA PEL 1000
OSHA STEL N/E
NIOSH REL 250
NIOSH IDLH 2500
0.1 - 1% 108-67-8 1,3,5-Trimethylbenzene 1.87
ACGIH TLV 25
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
NIOSH 25
0.1 - 1% 7732-18-5 Water N/A
ACGIH TLV
ACGIH STEL
OSHA PEL N/E
OSHA STEL N/E
NIOSH N/E
NIOSH N/E
5 - 20% 65997-17-3 Silica, amorphous, precipitated and gel N/A
ACGIH TLV N/E
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
0.1 - 1% 41556-26-7 Bis(1,2,2,6,6-Pentamethyl-4-piperidyl) Sebacate 7.5
ACGIH TLV N/E
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
0.1 - 1% 104810-48-2 Poly Alcohol .0000007
ACGIH TLV N/E
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
0.1 - 1% 104810-47-1 Poly alcohol .0000007
ACGIH TLV N/E
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
1 - 5% 9004-36-8 Cellulose Acetate Butyrate N/A
ACGIH TLV N/E
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
0.1 - 1% 82919-37-7 Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate 7.5
ACGIH TLV N/E
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
0.1 - 1% 526-73-8 N-Butanol 1.35
ACGIH TLV 25
ACGIH STEL N/E
OSHA PEL N/E
OSHA STEL N/E
NIOSH 25
5 - 20% 79-20-9 Methyl Acetate 173
ACGIH TLV 200
ACGIH STEL 250
OSHA PEL 200
OSHA STEL N/E
NIOSH REL-TWA: 200
NIOSH REL-STEL: 250
NIOSH IDLH 3100
5 - 20% 98-56-6 Parachlorobenzotriflouride 5.3
ACGIH TLV
ACGIH STEL
OSHA PEL
OSHA STEL
0.1 - 1% 169117-72-0 2,5,8,11-Tetramethyl-6-dodecyn-5,8-diol ethoxylate .05
ACGIH TLV
ACGIH STEL
OSHA PEL
OSHA STEL
===================================================================================================================
Section 3 -- HAZARDS IDENTIFICATION
===================================================================================================================
ROUTES OF EXPOSURE:
Exposure may be by INHALATION and/or SKIN or EYE contact, depending on conditions of use. To minimize exposure, follow recommendations for proper use, ventilation, and personal protective equipment.
EFFECTS OF OVEREXPOSURE:
Irritation of eyes, skin and upper respiratory system. May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.
SIGNS AND SYMPTOMS OF OVEREXPOSURE:
Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists. Redness and itching or burning sensation may indicate eye or excessive skin exposure.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:
None generally recognized.
CANCER INFORMATION:
FOR COMPLETE DISCUSSION OF TOXICOLOGY DATA REFER TO SECTION 11.
===================================================================================================================
Section 4 -- FIRST AID MEASURES
===================================================================================================================
If INHALED:
If affected, remove from exposure. Restore breathing. Keep warm and quiet.
If on SKIN:
Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use.
If in EYES:
Flush eyes with large amounts of water for 15 minutes. Get medical attention.
If SWALLOWED:
Do not induce vomiting. Get medical attention immediately.
Section 5 -- FIRE FIGHTING MEASURES
FLASH POINT LEL UEL
-4 F 0.3 16.0
EXTINGUISHING MEDIA:
Use National Fire Protection Association (NFPA) Class B extinguishers (carbon dioxide, dry chemical, or universal aqueous film forming foam) designed to extinguish NFPA Class IB flammable liquid fires. Water spray may be ineffective. Water spray may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
Containers may explode when exposed to extreme heat. Application to hot surfaces requires special precautions. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention.
SPECIAL FIRE FIGHTING PROCEDURES:
Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible auto ignition or explosion when exposed to extreme heat.
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Section 6 -- ACCIDENTAL RELEASE MEASURES
===================================================================================================================
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Provide maximum ventilation. Only personnel equipped with proper respiratory, skin, and eye protection should be permitted in the area. Remove all sources of ignition. Take up spilled material with sand, vermiculite, or other noncombustible absorbent material and place in clean, empty containers for disposal. Only the spilled material and the absorbent should be placed in this container.
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Section 7 -- HANDLING RELEASE MEASURES
===================================================================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Keep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively. During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off stoves, electric tools and appliances, and other sources of ignition. Consult NFPA Code. Use approved bonding and grounding procedures. Do not expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water, and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.
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Section 8 -- EXPOSURE CONTROLS / PERSONAL PROTECTION
===================================================================================================================
PRECAUTIONS TO BE TAKEN IN USE:
Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed "as Dust" in section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in section 2, the applicable limits for nuisance dust are ACGIII TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping, or other means may generate dust or fumes that contain lead.
VENTILATION:
Local exhaust preferable. General exhaust acceptable if the exposure to materials in section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.
RESPIRATORY PROTECTION:
If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive.
PROTECTIVE GLOVES:
None required for normal application of these products where minimal skin contact is expected. For long repeated contact, wear chemical resistant gloves.
EYE PROTECTION:
Wear safety spectacles with unperforated side shields.
OTHER PRECAUTIONS:
Intentional misuse by deliberately concentrating and inhaling the contents can be harmful of fatal.
===================================================================================================================
Section 9 -- PHYSICAL AND CHEMICAL PROPERTIES
===================================================================================================================
PRODUCT WEIGHT 9.001 lb/gal 1079 g/l
SPECIFIC GRAVITY 1.080
BOILING POINT 0 - 599 F 18 - 315 C
VOLATILES 68.3 % by wt 72.3 % by vol
EVAPORATION RATE Same as ether
VAPOR DENSITY Heavier than air
REGULATORY VOC 2.38 lb/gal 285 g/l
ACTUAL VOC 1.01 lb/gal 121 g/l
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Section 10 -- STABILITY AND REACTIVITY
===================================================================================================================
STABILITY:
This product is normally stable and will not undergo hazardous reactions.
CONDITIONS TO AVOID:
None Known.
INCOMPATIBILITY:
Avoid contact with strong alkalies, strong mineral acids, or strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
Carbon monoxide, carbon dioxide, oxides of sulfur, oxides of barium, lowers molecular weight polymer fractions.
HAZARDOUS POLYMERIZATION:
None Known.
===================================================================================================================
Section 11 -- TOXICOLOGICAL INFORMATION
===================================================================================================================
CAS No. Ingredient Name
------------------------------------------------------------------------------------------------------------
1330-20-7 Xylene
IARC Classification Group 3
Acute oral toxicity: LD50 Rat: 4.300 mg/kg
Acute inhalation toxicity: No data available
Acute dermal toxicity: LD50 Rabbit: (>) 2,000 mg/kg
100-41-4 ethylbenzene
IARC Classification Group 2B
Toxicological Information:
Draize test, rabbit, eye: 500 mg Severe;
Inhalation, mouse: LC50 = 35500 mg/m3/2H;
Inhalation, rat: LC50 = 55000 mg/m3/2H;
Oral, rat: LD50 = 3500 mg/kg;
Oral, rat: LD50 = 3500 mg/kg;
Skin, rabbit: LD50 = 17800 uL/kg;
Inhalation rat LC50: 17.2 mg/l/4H from BASF.
Carcinogenicity: Confirmed animal carcinogen with unknown relevance to
Humans California: carcinogen, initial date 6/11/04
NTP: Not listed.
IARC: Group 2B carcinogen
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: Mutation in mammalian somatic cells(Rodent, mouse)
Lymphocyte = 80 mg/L.
Neurotoxicity: No information found
Other Studies:
110-43-0 Methyl n-Amyl Ketone
IARC Classification Not Established
ACUTE ORAL TOXICITY: LD50 RAT: 1,670 MG/KG
ACUTE INHALATION TOXICITY: LCL0 RAT: 4000 PPM, 4 H
ACUTE DERMAL TOXICITY: LD50 RABBIT: 13,000 MG/KG
95-63-6 1,2,4-Trimethylbenzene
IARC Classification Not Established
LC50/LD50
Inhalation, rat: LC50 = 18000 mg/m3/4H;
Oral, mouse: LD50 = 6900 mg/kg;
Oral, rat: LD50 = 5 gm/kg;
Carcinogenicity: CAS# 95-63-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: Workers exposed to a mixture of trimethylbenzenes at up to 60
ppm experienced CNS changes, asthmatic bronchitis, and blood
dyscrasias. Contamination of the solvent with benzene was
probably responsible for the blood abnormalities.
Teratogenicity: No information available.
Reproductive Effects: No information found
Mutagenicity: CAS# 95-63-6: Sister Chromatid Exchange: Intraperitoneal,
mouse = 900 mg/kg.
Neurotoxicity: No information found
67-64-1 Acetone
IARC Classification Not Established
Acute oral toxicity LD50 Rat: 5,800 mg/kg
Acute inhalation toxicity LC50 Rat: >16000 ppm, 4 h
Acute dermal toxicity LD50 Rabbit: >20,000 mg/kg
108-67-8 1,3,5-Trimethylbenzene
IARC Classification Not Established
RTECS#:
CAS# 108-67-8: OX6825000
LD50/LC50:
CAS# 108-67-8: Draize test, rabbit, eye: 500 mg/24H Mild; Draize test,
rabbit, skin: 20 mg/24H Moderate;
Inhalation, rat: LC50 = 24000 mg/m3/4H;
Oral, mouse: LD50 = 7000 mg/kg;
Oral, rat: LD50 = 5000 mg/kg;
Carcinogenicity:
CAS# 108-67-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: Mutagenic effects have occurred in experimental animals.
Neurotoxicity: No information found
Other Studies:
7732-18-5 Water
IARC Classification Not Established
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No Data.
Teratogenicity: No information found.
Reproductive Effects: No information found.
Neurotoxicity: No information found.
Mutagenicity: No information found.
Other Studies: See actual entry in RTECS for complete information.
112926-00-8 Silica, amorphous, precipitated and gel
IARC Classification Not Established
No Data Available
41556-26-7 Bis(1,2,2,6,6-Pentamethyl-4-piperidinyl) Sebacate
IARC Classification Not Established
Acute toxicity
Oral: LD50/rat: > 2,000 mg/kg
Skin irritation: rabbit: non-irritant
Eye irritation : rabbit: non-irritant
Sensitization: guinea pig: sensitizing (OECD Guideline 406)
104810-48-2 Poly alcohol
IARC Classification Not Established
Acute toxicity
Oral: Type of value: LD50
Species: rat Value: > 2,000 mg/kg (OECD Guideline 401)
Inhalation: Type of value: LC50 Species: rat Value: > 5.8 mg/l (OECD
Guideline 403) Exposure time: 14 d
Dermal: Type of value: LD50 Species: rat Value: > 2,000 mg/kg (OECD Guideline 402) Irritation / corrosion
Skin: Species: rabbit
Result: non-irritant
Method: OECD Guideline 404
Eye: Species: rabbit
Result: non-irritant
Method: OECD Guideline 405
Information on: Polyethylene glycol
Sensitization: Species: guinea pig
Result: Caused skin sensitization in animal studies.
Method: OECD Guideline 406
Repeated dose toxicity
Experimental/calculated data: No data available concerning repeated dose toxicity.
Other Information: The product has not been tested. The statements on toxicology
have been derived from the properties of the individual
components.
104810-47-1 Poly alcohol
IARC Classification Not Established
Acute toxicity
Oral: Type of value: LD50
Species: rat Value: > 2,000 mg/kg (OECD Guideline 401)
Inhalation: Type of value: LC50 Species: rat Value: > 5.8 mg/l (OECD
Guideline 403) Exposure time: 14 d
Dermal: Type of value: LD50 Species: rat Value: > 2,000 mg/kg (OECD
Guideline 402) Irritation / corrosion
Skin: Species: rabbit
Result: non-irritant
Method: OECD Guideline 404
Eye: Species: rabbit
Result: non-irritant
Method: OECD Guideline 405
Information on: Polyethylene glycol
Sensitization:
Species: guinea pig
Result: Caused skin sensitization in animal studies.
Method: OECD Guideline 406
Repeated dose toxicity
Experimental/calculated data: No data available concerning repeated dose toxicity.
Other Information: The product has not been tested. The statements on toxicology been derived from the properties of the individual
components.
9004-36-8 Cellulose Acetate Butyrate
IARC Classification Not Established
Oral LD-50: (rat) >6,400 mg/kg(highest dose tested)
Dermal LD-50: (guinea pig) > 1,000 mg/kg (highest dose tested)
Skin Irritation (guinea pig) slight
Skin Sensitization: (guinea pig) none
82919-37-7 Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate
IARC Classification Not Established
Acute toxicity
Oral: LD50/rat: > 2,000 mg/kg
Skin irritation: rabbit: non-irritant
Eye irritation : rabbit: non-irritant
Sensitization: guinea pig: sensitizing (OECD Guideline 406)
526-73-8 N-Butanol
IARC Classification Not Established
LD50/LC50: Not available.
Oral, rat: LD50 = >90 mL/kg;
Carcinogenicity:
CAS# 526-73-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: Mutagenic effects have occurred in experimental animals.
Neurotoxicity: No information available.
Other Studies:
79-20-9 Methyl Acetate
IARC Classification Not Established
Oral: LD50: >5000 mg/kg, rat
Dermal: LD50: >2000 mg/kg, rat
Inhalation: LC50: >49 mg/l, rat 4h
Skin Irritation: Non-irritant
Species Rabbit
Method OECD 404
Eye Irritation: Irritant
Species Rabbit eye
Method OECD 405
In vitro Mutagenicity: Ames test-negative with and without metabolic activation
In vitro Mutagenicity: Mutagenicity (micronucleus test)-negative Rat Inhalation
98-56-6 Parachlorobenzotriflouride
IARC Classification Not Established
Acute oral toxicity: LD50 rat: >6.8g/kg
Acute inhalation toxicity: LC50 Rat: 4479ppm, 4h
Acute dermal toxicity: LD50 rabbit: >2.7 g/kg
169117-72-0 2,5,8,11-Tetramethyl-6-dodecyn-5,8-diol ethoxylate
IARC Classification Not Established
Acute oral toxicity: LD50 Rat: 2000 mg/kg
Acute inhalation toxicity: No data available
Skin toxicity: LD50 Rabbit: 2,000 mg/kg
Eye irritation: Severe eye irritation
Acute dermal: Mild skin irritation
irritation/corrosion Not mutagenic in AMES Test.
IARC Reference
IARC Group 1: The agent is carcinogenic to humans
This category is used when there is sufficient evidence of carcinogenicity in humans. Exceptionally, an agent may be placed in this category when evidence of carcinogenicity in humans is less than sufficient but there is sufficient evidence of carcinogenicity in experimental animals and strong evidence in exposed humans that the agent acts through a relevant mechanism of carcinogenicity.
IARC Group 2A: The agent is probably carcinogenic to humans.
This category is used when there is limited evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals. In some cases, an agent may be classified in this category when there is inadequate evidence of carcinogenicity in humans and sufficient evidence of carcinogenicity in experimental animals and strong evidence that the carcinogenesis is mediated by a mechanism that also operates in humans. Exceptionally, an agent may be classified in this category solely on the basis of limited evidence of carcinogenicity in humans. An agent may be assigned to this category if it clearly belongs, based on mechanistic considerations, to a class of agents for which one or more members have been classified in Group 1 or Group 2A.
IARC Group 2B: The agent is possibly carcinogenic to humans.
This category is used for agents for which there is limited evidence of carcinogenicity in humans and less than sufficient evidence of carcinogenicity in experimental animals. It may also be used when there is inadequate evidence of carcinogenicity in humans but there is sufficient evidence of carcinogenicity in experimental animals. In some instances, an agent for which there is inadequate evidence of carcinogenicity in humans and less than sufficient evidence of carcinogenicity in experimental animals together with supporting evidence from mechanistic and other relevant data may be placed in this group. An agent may be classified in this category solely on the basis of strong evidence from mechanistic and other relevant data.
IARC Group 3: The agent is not classifiable as to its carcinogenicity to humans.
This category is used most commonly for agents for which the evidence of carcinogenicity is inadequate in humans and inadequate or limited in experimental animals. Exceptionally, agents for which the evidence of carcinogenicity is inadequate in humans but sufficient in experimental animals may be placed in this category when there is strong evidence that the mechanism of carcinogenicity in experimental animals does not operate in humans. Agents that do not fall into any other group are also placed in this category. An evaluation in Group 3 is not a determination of non-carcinogenicity or overall safety. It often means that further research is needed, especially when exposures are widespread or the cancer data are consistent with differing interpretations.
IARC Group 4: The agent is probably not carcinogenic to humans.
This category is used for agents for which there is evidence suggesting lack of carcinogenicity in humans and in experimental animals. In some instances, agents for which there is inadequate evidence of carcinogenicity in humans but evidence suggesting lack of carcinogenicity in experimental animals, consistently and strongly supported by a broad range of mechanistic and other relevant data, may be classified in this group.
===================================================================================================================
Section 12 -- ECOLOGICAL INFORMATION
===================================================================================================================
CAS No. Ingredient Name
------------------------------------------------------------------------------------------------------------
1330-20-7 Xylene
Biodegradability: No data available
Bioaccumulation: No Data Available
Ecotoxicity effects
Toxicity to fish: 96h LC50 Flathead minnow (oimephales promelas); 23.53-
29.97 mg/l
Method: Static
Mortality
Toxicity to daphnia and other aquatic Invertebrates: 24h LC50 Water flea (Daphnia
magna): > 100.00 -<1,000.00 mg/l
Method: Static
Mortality
Toxicity to algae: No data available
Toxicity to bacteria: No data available
Biochemical Oxygen Demand (COD): No data available
Chemical Oxygen Demand (COD): No data available
Additional ecological information: No data available
100-41-4 ethylbenzene
Ecological Information
Ecotoxicity: Fish: Rainbow trout: LC50 = 14.0 mg/L; 96 Hr.; Static
Bioassay Fish: Fathead Minnow: LC50 = 12.1 mg/L; 96 Hr.;
Flow-through Bioassay Fish: Bluegill/Sunfish: LC50 =
150.0mg/L; 96 Hr.; Static Bioassay, pH 6.5-7.9, 21-23
degrees C Water flea EC50 = 2.1 mg/L; 48 Hr.; Static
Bioassay Water flea EC50 = 75.0 mg/L; 48 Hr.; Static
Bioassay Shrimp (mysidoposis bahia),
LC50=87.6 mg/L/96hr. Sheepshead minnow LC50=275
mg/L/96hr. Fathead minnow LC50=42.3 mg/L/96hr in hard
water &48.5 mg/L/96hr in soft water.
Environmental: Experimental data on the bioconcentration of
ethylbenzene include a log BCF of 1.9 in goldfish and
the log BCF of 0.67 for clams exposed to the water-
soluble fraction of crude oil. Using its octanol/water
partition coefficient (log Kow= 3.15) and using a
recommended regression equation, one can calculate a log
BCF in fish of 2.16 indicating that ethylbenzene should
not significantly bioconcentrate in aquatic organisms.
Ethylbenzene has a moderate adsorption for soil. The
measured Koc for silt loam was 164 Physical: The
predominant photochemical reaction of ethylbenzene in
the atmosphere is with hydroxyl radicals; the
tropospheric half-life for this reaction is 5.5 and 24
hr in the summer and winter, actively. Degradation is
somewhat faster under photochemical smog situations.
Photooxidation products which have been identified
include ethylphenol, benzaldehyde, acetophenone and
m- and p-ethylnitrobenzene. Ethylbenzene is resistant to
hydrolysis. Ethylbenzene does not significantly absorb
light above 290 nm in methanol solution.
110-43-0 Methyl n-Amyl Ketone NO DATA AVAILABLE
95-63-6 1,2,4-Trimethylbenzene
Ecotoxicity: Fish: Fathead Minnow: LC50 = 77.2 mg/L; 96 Hr; CAS# 95-
63-6: Flow-through at 25 C (pH 7.24) CAS# 95-63-6:
Estimated Koc value = 720. 1,2,4-trimethylbenzene will
have low mobility in soil. Volatilization from moist and
dry soil surfaces is expected to occur. 1,2,4-
Trimethylbenzene is expected to aerobically biodegrade
in both soil and water. Anaerobic aquifer microcosms did
not show significant biodegradation in comparison to
poisoned controls. In water, 1,2,4-trimethylbenzene may
adsorb to sediment or particulate matter.
Environmental: CAS# 95-63-6: Bioconcentration in aquatic organisms is
moderate to high based on BCF values of 31-275, measured
in carp. 1,2,4-Trimethylbenzene is expected to
photodegrade in natural waters. If released to the
atmosphere, 1,2,4-trimethylbenzene will exist solely in
the vapor phase in the ambient atmosphere. Vapor-phase
1,2,4-trimethylbenzene is degraded in the atmosphere by
reaction with photochemically-produced hydroxyl radicals
and nitrate radicals with half-lives of about 12 hours
and 6-30 days, respectively.
Physical: No information available.
Other: No information available.
67-64-1 Acetone
Biodegradability: no data available
Bioaccumulation: no data available
Ecotoxicity to fish: 96 h LC50 Rainbow trout, donaldson trout (Oncorhynchus
mykiss): 4,740.00-6,330.00 mg/l
Method: Static Mortality 96 h LC50 Bluegill (Lepomis
macrochirus): 8,300.00 mg/l
Method: Static
Mortality 96 h LC50 Fathead minnow (Pimephales
promelas): 8,733.00-9,482.00 mg/l Method: Flow through
Mortality
Toxicity to daphnia and other aquatic invertebrates: no data available
Toxicity to algae: no data available
Toxicity to bacteria: no data available
Biochemical Oxygen Demand (BOD): no data available
Chemical Oxygen Demand (COD): no data available
Additional ecological information: no data available
108-67-8 1,3,5-Trimethylbenzene
Ecotoxicity: Fish: Fathead Minnow: LC50 = 3.48 mg/L; 96 Hr;
Unspecified Fish: Goldfish: LC50 = 12.5-13.0 mg/L; 96 Hr;
Unspecified Fish: Goldfish: LC50 = 13.7 mg/L; 72 Hr;
Unspecified Water flea Daphnia: EC50 = 50 mg/L; 72 Hr;
Unspecified No data available.
Environmental: According to a classification scheme, BCF values of 23
to 342, measured in carp, suggest that bioconcentration
in aquatic organisms may occur. Biodegradation may be an
important fate process for this compound in water;
acclimation may increase the rate of biodegradation.
Physical: No information found.
Other: Do not empty into drains.
7732-18-5 Water
Ecotoxicity: No data available. No information available.
Environmental: Expected to evaporate.
Physical: No information available.
Other: No information available.
112926-00-8 Silica, amorphous, precipitated and gel
No Data Available
41556-26-7 Bis(1,2,2,6,6-Pentamethyl-4-piperidinyl) Sebacate
Environmental fate and transport
Biodegradation: Evaluation: Moderately/partially biodegradable.
Not readily biodegradable (by OECD criteria).
Environmental toxicity
Acute and prolonged toxicity to fish: OECD 203; ISO 7346; 92/69/EEC, C.1
sunfish/LC50 (96 h): 0.97 mg/l
OECD 203; ISO 7346; 92/69/EEC, C.1 Rainbow trout/LC50
(96 h): 7.9 mg/l
Acute toxicity to aquatic invertebrates: OECD Guideline 202, part 1 Daphnia
magna/EC50 (24 h): 20 mg/l
Toxicity to microorganisms: OECD Guideline 209 activated sludge/EC50 (3 h): >
100 mg/l
104810-48-2 Poly alcohol
Fish
Acute: OECD Guideline 203 LC50: 2.8 mg/l
Aquatic invertebrates
Acute: OECD Guideline 202, part 1 Daphnia magna/EC50: 3.8 mg/l
Aquatic plants
Toxicity to aquatic plants: OECD Guideline 201 unspecified algae/EC50: > 9 mg/l
The value meets the highest applied test concentration.
No toxic effects occur within the range of solubility.
Degradability / Persistence
Biological / Abiological Degradation
Test method: OECD 301B; ISO 9439; 92/69/EEC, C.4-C
Evaluation: Poorly biodegradable.
Other adverse effects: Do not allow to enter soil, waterways or waste water
channels. Inhibition of degradation activity in
activated sludge is not to be anticipated during correct
introduction of low concentrations.
104810-47-1 Poly alcohol
Fish
Acute: OECD Guideline 203 LC50: 2.8 mg/l
Aquatic invertebrates
Acute: OECD Guideline 202, part 1 Daphnia magna/EC50: 3.8 mg/l
Aquatic plants
Toxicity to aquatic plants: OECD Guideline 201 unspecified algae/EC50: > 9 mg/l
The value meets the highest applied test concentration.
No toxic effects occur within the range of solubility.
Degradability / Persistence
Biological / Abiological Degradation
Test method: OECD 301B; ISO 9439; 92/69/EEC, C.4-C
Evaluation: Poorly biodegradable.
Other adverse effects: Do not allow to enter soil, waterways or waste water channels. Inhibition of degradation activity in
activated sludge is not to be anticipated during correct
introduction of low concentrations.
9004-36-8 Cellulose Acetate Butyrate No data available.
82919-37-7 Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate
Environmental fate and transport
Biodegradation: Evaluation: Moderately/partially biodegradable.
Not readily biodegradable (by OECD criteria).
Environmental toxicity
Acute and prolonged toxicity to fish: OECD 203; ISO 7346; 92/69/EEC, C.1
sunfish/LC50 (96 h): 0.97 mg/l OECD 203; ISO 7346;
92/69/EEC, C.1 Rainbow trout/LC50 (96 h): 7.9 mg/l
Acute toxicity to aquatic invertebrates: OECD Guideline 202, part 1 Daphnia
magna/EC50 (24 h): 20 mg/l
Toxicity to microorganisms: OECD Guideline 209 activated sludge/EC50 (3 h): > 100
mg/l
526-73-8 N-Butanol
No information available.
79-20-9 Methyl Acetate
Toxicity to fish LC50: >250mg/l (96h)
Species Brachidanio rerio (zebra fish)
Method OECH 203
Toxicity to daphnia EC50: >1000 mg/l (48h)
Species Daphnia magna
Method OECD 202
Toxicity to Algae EC50: >120 mg/l (72h)
Species Scenedesmus subspicatus
Method OECD 201
Biodegradation 70% (28d)
Method OECD 301 D
98-56-6 Parachlorobenzotriflouride
Aquatic toxicity
Acute and Prolonged Toxicity to fish: no data
Acute Toxicity to Aquatic Invertebrates: no data
Environmental fate and pathways: no data
169117-72- 2,5,8,11-Tetramethyl-6-dodecyn-5,8-diol ethoxylate
Aquatic toxicity
Acute and Prolonged Toxicity to Fish: No data
Acute Toxicity to Aquatic Invertebrates: No data
Environmental fate and pathways: No data
===================================================================================================================
Section 13 -- DISPOSAL CONSIDERATIONS
===================================================================================================================
WASTE DISPOSAL METHOD:
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State, and Local regulations regarding pollution.
===================================================================================================================
Section 14 -- TRANSPORT INFORMATION
===================================================================================================================
Proper Shipping Name: Consumer Commodity
NOS Technical Name: ORM-D
Hazard Class: N/A
UN Number: N/A
Packing Group: N/A
===================================================================================================================
Section 15 -- REGULATORY INFORMATION
===================================================================================================================
Canadian Regulations:
CEPA (Canadian Environmental Protection Act):
All substances in this product are listed on the Canadian Domestic Substance List (DSL) or are not required to be listed.
US Regulations:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372.
SARA 313:
CAS No. CHEMICAL/COMPOUND % by WT
------------------------------------------------------------------------------------------------------------
1330-20-7 Xylene 0.2
100-41-4 ethylbenzene 0.1
95-63-6 1,2,4-Trimethylbenzene 1.6
67-64-1 Acetone 17.4
PROP 65
CAS No. CHEMICAL COMPOUND % by WT
------------------------------------------------------------------------------------------------------------
100-41-4 ethylbenzene 0.1
TSCA CERTIFICATION:
U.S. TSCA: This product and/or all of its components are listed on the U.S. TSCA Inventory or is otherwise exempt form TSCA Inventory reporting requirements.
===================================================================================================================
Section 16 -- OTHER INFORMATION
===================================================================================================================
DISCLAIMER:
Do not handle until the manufacturer's safety precautions have been read and understood. Regulations require that all employees be trained on Material Safety Data Sheets for all products with which they come in contact. While we believe that the data contained herein is accurate and derived from qualified sources, the data are not to be taken as a warranty or representation for which we assume legal responsibility. They are offered solely for your consideration, investigation, and verification. Any use of these data and information must be determined by the user to be in accordance with applicable federal, state, provincial, and local laws and regulations.
__________________________________________________________________________________________________________
ENVIRONMENTAL DATA SHEET
All data given below are MAXIMUM THEORETICAL VALUES based on the product AS CURRENTLY FORMULATED. Variations may occur on individual batches due to adjustments made during production.
PRODUCT NUMBER
CP3820
PRODUCT NAME
Matte Clear 2.8 VOC
PRODUCT WEIGHT SPECIFIC GRAVITY FLASH POINT
9.001 lb/gal 1.080 -4 F
CERC. SARA HAPS PCT PCT
VOLATILE INGREDIENTS CAS. NO. 313 112 by by
NAME TC Wt Vol
___________________________________________________________________________________________________________
Xylene 1330-20-7 X X X 0.2 0.3
ethylbenzene 100-41-4 X X X 0.1 0.1
Methyl n-Amyl Ketone 110-43-0 X 5.8 7.7
1,2,4-Trimethylbenzene 95-63-6 X X 1.6 2.1
Acetone 67-64-1 X X 17.4 23.8
1,3,5-Trimethylbenzene 108-67-8 X 0.7 0.8
Water 7732-18-5 X 0.5 0.5
Silica, amorphous, precipitated and gel1 12926-00-8 X 6.4 3.3
Bis(1,2,2,6,6-Pentamethyl-4-piperidinyl) Sebacate 41556-26-7 X 0.8 0.7
Poly alcohol 104810-48-2 X 0.2 0.2
Poly alcohol 104810-47-1 X 0.2 0.2
Cellulose Acetate Butyrate 9004-36-8 X 2.0 2.0
Methyl 1,2,2,6,6-pentamethyl-4-piperidyl sebacate 82919-37-7 X 0.3 0.2
N-Butanol 526-73-8 X 0.2 0.2
Methyl Acetate 79-20-9 X 5.1 5.9
Parachlorobenzotriflouride 98-56-6 X 18.6 14.9
2,5,8,11-Tetramethyl-6-dodecyn-5,8-diol ethoxylate 169117-72-0 X 0.1 0.1
____________________________________________________________________________________________________________
VOLATILE ORGANIC COMPOUNDS
A. Coating Density 9.00 lb/gal 1079 g/l
B. Total Volatiles 68.3 % by wt 72.3 % by vol
Exempt Volatiles 57.1 % by wt 57.7 % by vol
Water 0.0 % by wt 0.0 % by vol
C. Organic Volatiles 11.2 % by wt 14.6 % by vol
D. Percent Non-Volatile 31.7 % by wt 27.7 % by vol
E. Regulatory VOC 2.38 lb/gal 285 g/l
Actual VOC 1.01 lb/gal 121 g/l
Solids 2.85 lb/gal 342 g/l
WASTE DISPOSAL
Waste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers. The addition of reducers or other additives to this product may substantially alter the above data. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.